Use of Plant-Based Coagulants Sorghum Bicolor and Trifolium Repens as Future Alternatives for Textile Wastewater Treatment Based on Computational Model

Authors

  • Hanieh Mirbolooki The Academic Center for Education, Culture and Research (ACECR), Environmental Research Institute, Iran
  • Mehran Parsa University of Tehran, Iran
  • Shamim Moghadami The Academic Center for Education, Culture and Research, Environmental Research Institute, Iran
  • Fatemeh Ghanbari The Academic Center for Education, Culture and Research, Environmental Research Institute, Iran
  • Fariba Ostovar The Academic Center for Education, Culture and Research, Environmental Research Institute, Iran

DOI:

https://doi.org/10.61360/BoniGHSS242016120301

Keywords:

plant-based coagulant, COD reduction, turbidity reduction, Sorghum bicolor, Trifolium repens, computational model

Abstract

Sorghum bicolor and Trifolium repens extracts as plant coagulants can be used for wastewater treatment instead of chemical coagulants. This study investigates the effects of pH and coagulant dose on COD and turbidity reduction by natural coagulants. In the optimum treatment conditions of 100 mg/L coagulant dose and pH 7, high turbidity (81.34%), and COD reduction (62%) (compared with alum and FeCl3) were obtained. The percentage of COD reduction is higher in Trifolium repens than the other plant coagulant, and the percentage of turbidity reduction is higher in Sorghum bicolor. FT-IR spectra were performed on the plant extracts to identify the existing factors in active extracts. Also, outlet COD and turbidity values can be predicted and calculated according to computational equation in similar treatment systems. It should be mentioned that the only applied solvent for extracting the natural coagulant seeds was distilled water, and none of the other solvents such as NaCl and NaOH were used. According to the results, the characteristics of the treated effluents by the plant extracts make them appropriate alternatives for textile wastewater treatment.

References

Abidin, Z. Z., Shamsudin, N. S. M., Madehi, N., & Sobri, S. (2013). Optimisation of a method to extract the active coagulant agent from Jatropha curcas seeds for use in turbidity removal. Industrial Crops and Products, 41, 319–323.

Ang, W. L., & Mohammad, A. W. (2020). State of the art and sustainability of natural coagulants in water and wastewater treatment. Journal of Cleaner Production, 262, 121267.

Antov, M.G.,Š´ciban, M.B., &Prodanovi´c,J.M.(2012).Evaluation of the efficiency of natural coagulant obtained by ultrafiltration of common bean seed extract in water turbidity removal. Ecological engineering, 49,48–52.

Awad, M., Wang, H., & Li, F. (2013). Preliminary study on combined use of Moringa seeds extract and PAC for water treatment. Research Journal of Recent Sciences, 2(8), 52–55.

Balbinoti, J. R., dos Santos, Jr, R. E., de Sousa, L. B. F., de Jesus Bassetti, F., Balbinoti, T. C. V., Jorge, R. M. M., & de Matos Jorge, L. M. (2023). Plant-based coagulants for food industry wastewater treatment. Journal of Water Process Engineering, 52, 103525.

Banihabib, M. E., Vaziri, B., & Javadi, S. (2018). A model for the assessment of the effect of mulching on aquifer recharging by rainfalls in an arid region. Journal of Hydrology, 567, 102–113.

Beltrán-Heredia, J., Sánchez-Martín, J., & Dávila-Acedo, M. A. (2011). Optimization of the synthesis of a new coagulant from a tannin extract. Journal of Hazardous Materials, 186(2–3), 1704–1712.

Beltrán-Heredia, J., Sánchez-Martín, J., & Delgado-Regalado, A. (2009). Removal of carmine indigo dye with Moringa oleifera seed extract. Industrial & Engineering Chemistry Research, 48(14), 6512–6520.

Camacho, F. P., Sousa, V. S., Bergamasco, R., & Teixeira, M. R. (2017). The use of Moringa oleifera as a natural coagulant in surface water treatment. Chemical Engineering Journal, 313, 226–237.

Chaibakhsh, N., Ahmadi, N., & Zanjanchi, M. A. (2014). Use of Plantago major L. as a natural coagulant for optimized decolorization of dye-containing wastewater. Industrial Crops and Products, 61, 169–175.

Chen, Z., Zhang, W., Tang, X.,Fan, H., Xie, X., Wan,Q., &Tang,J. Z. (2016). Extraction and characterization of polysaccharides from Semen Cassiae by microwave-assisted aqueous two phase extraction coupled with spectroscopy and HPLC. Carbohydrate Polymers, 144, 263–270.

Choy, S. Y., Prasad, K. M. N., Wu, T.Y., &Ramanan,R. N.(2015). A review on common vegetables and legumes as promising plant-based natural coagulants in water clarification. International Journal of Environmental Science and Technology, 12, 367–390.

Chylińska, M., Szymańska-Chargot, M., & Zdunek, A. (2016). FT-IR and FT-Raman characterization of non-cellulosic polysaccharides fractions isolated from plant cell wall. Carbohydrate Polymers, 154,48–54.

Crouzier, T., Boudou, T., & Picart, C. (2010). Polysaccharide-based polyelectrolyte multilayers. Current Opinion in Colloid & Interface Science, 15(6), 417–426.

Dial, H. L. (2012). Plant guide for Sorghum (Sorghum bicolor L.). USA: Tucson Plant Materials Center. Dong, H., Lin, S., Zhang, Q., Chen, H., Lan, W., Li, H., He, J., & Qin, W. (2016). Effect of extraction methods on the properties and antioxidant activities of Chuanminshen violaceum polysaccharides. International Journal of Biological Macromolecules, 93, 179–185.

American Water Works Association and Water Environment Federation. (2005). Standard methods for the examination of water and wastewater. USA: American Public Health Association.

Feng, Y., Ling, L., Fan, H., Liu, Y., Tan, F., Shu, Y., & Wang, J. (2011). Effects of temperature, water content and pH on degradation of Cry1Ab protein released from Bt corn straw in soil. Soil Biology and Biochemistry, 43(7), 1600–1606.

Freitas, T. K. F.S.,Oliveira, V.M.,DeSouza,M.T.F.,Geraldino,H. C. L., Almeida, V. C., Fávaro, S. L., & Garcia, J. C. (2015). Optimization of coagulation-flocculation process for treatment of industrial textile wastewater using okra (A. esculentus) mucilage as natural coagulant. Industrial Crops and Products, 76, 538–544.

Gautam, S., & Saini, G. (2020). Use of natural coagulants for industrial wastewater treatment. Global Journal of Environmental Science and Management, 6(4), 553–578.

Gharbani, P., & Mehrizad, A. (2022). Preparation and characterization of graphitic carbon nitrides/polyvinylidene fluoride adsorptive membrane modified with chitosan for Rhodamine B dye removal from water: Adsorption isotherms, kinetics and thermodynamics. Carbohydrate Polymers, 277, 118860.

Ghebremichael, K. A., Gunaratna, K. R., & Dalhammar, G. (2006). Single-step ion exchange purification of the coagulant protein from Moringa oleifera seed. Applied Microbiology and Biotechnology, 70, 526–532.

Golmohammadi, G., Rudra, R. P., Parkin, G. W., Kulasekera, P. B., Macrae, M., & Goel, P. K. (2020). Assessment of impacts of climate change on tile discharge and nitrogen yield using the DRAINMOD model. Hydrology, 8(1), 1.

Gosavi, V. D., & Sharma, S. (2014). A general review on various treatment methods for textile wastewater. Journal of Environmental Science, Computer Science and Engineering &Technology, 3(1), 29–39.

Gulicovski, J. J., Čerovi´c, L. S., & Milonji´ c, S. K. (2008). Point of zero charge and isoelectric point of alumina. Materials and Manufacturing Processes, 23(6), 615–619.

Guo,R.,Cao,N.,Wu,Y.,&Wu,J.(2016).Optimized extraction and molecular characterization of polysaccharides from Sophora alopecuroides L. seeds. International Journal of Biological Macromolecules, 82, 231–242.

Horwitz, W. (1975). Official methods of analysis. USA: Association of Official Analytical Chemists.

Javadi, S., Kardan Moghaddam, H., & Neshat, A. (2022). A new approach for vulnerability assessment of coastal aquifers using combined index. Geocarto International, 37(6), 1681–1703.

Motaleb, M. A. (2011). Selected medicinal plants of Chittagong hill tracts. Bangladesh: Policy Commons.

Nigam,P.,Banat, I. M.,Singh, D.,&Marchant,R.(1996).Microbial process for the decolorization of textile effluent containing azo, diazo and reactive dyes. Process Biochemistry, 31(5), 435–442.

Popli, S., & Patel, U. D. (2015). Destruction of azo dyes by anaerobic–aerobic sequential biological treatment: A review. International Journal of Environmental Science and Technology, 12, 405–420.

Rasool, M. A., Tavakoli, B., Chaibakhsh, N., Pendashteh, A. R., & Mirroshandel, A. S. (2016). Use of a plant-based coagulant in coagulation–ozonation combined treatment of leachate from a waste dumping site. Ecological Engineering, 90, 431–437.

Razavi, S. M., Mortazavi, S. A., Matia-Merino, L., Hosseini-Parvar, S. H., Motamedzadegan, A., & Khanipour, E. (2009). Optimisation study of gum extraction from Basil seeds (Ocimum basilicum L.). International Journal of Food Science & Technology, 44(9), 1755–1762.

Sanghi, R., Bhattacharya, B., & Singh, V. (2006). Use of Cassia javahikai seed gum and gum-g-polyacrylamide as coagulant aid for the decolorization of textile dye solutions. Bioresource Technology, 97(10), 1259–1264.

Sarwan, B., Pare, B., Acharya, A. D., & Jonnalagadda, S. B. (2012). Mineralization and toxicity reduction of textile dye neutral red in aqueous phase using BiOCl photocatalysis. Journal of Photochemistry and Photobiology B: Biology, 116,48–55.

Sayyad, G., Vasel, L., Besalatpour, A. A., Gharabaghi, B., & Golmohammadi, G. (2015). Modeling blue and green water resources availability in an Iranian data scarce watershed using SWAT. Journal of Water Management Modeling.

Shak, K. P. Y., & Wu, T. Y. (2014). Coagulation–flocculation treatment of high-strength agro-industrial wastewater using natural Cassia obtusifolia seed gum: Treatment efficiencies and flocs characterization. Chemical Engineering Journal, 256, 293–305.

Shamsnejati, S., Chaibakhsh, N., Pendashteh, A. R., & Hayeripour, S. (2015). Mucilaginous seed of Ocimum basilicum as a natural coagulant for textile wastewater treatment. Industrial Crops and Products, 69,40–47.

Shull, J. M., Watterson, J. J., & Kirleis, A. W. (1991). Proposed nomenclature for the alcohol-soluble proteins (kafirins) of Sorghum bicolor (L. Moench) based on molecular weight, solubility, and structure. Journal of Agricultural and Food Chemistry, 39(1), 83–87.

Wang,J., Ge,B.,Li, Z.,Guan, F.,&Li, F.(2016).Structural analysis and immunoregulation activity comparison of five polysaccharides from Angelica sinensis. Carbohydrate Polymers, 140,6–12.

Wang,X.,Guo,Y.,Jia, Z., Ma, H., Liu, C., Liu, Z., & Hu, Y.(2021). Fabrication of graphene oxide/polydopamine adsorptive membrane by stepwise in-situ growth for removal of rhodamine B from water. Desalination, 516, 115220.

Yin, C. Y. (2010). Emerging usage of plant-based coagulants for water and wastewater treatment. Process Biochemistry, 45(9), 1437–1444.

Yu, P. (2008). Molecular chemistry of plant protein structure at a cellular level by synchrotron-based FTIR spectroscopy: Comparison of yellow (Brassica rapa) and Brown (Brassica napus) canola seed tissues. Infrared Physics & Technology, 51(5), 473–481.

Zhao, H., Liu, H., & Qu, J. (2009). Effect of pH on the aluminum salts hydrolysis during coagulation process: Formation and decomposition of polymeric aluminum species. Journal of Colloid and Interface Science, 330(1), 105–112

Downloads

Published

2024-03-08

Issue

Section

Research Article

How to Cite

Use of Plant-Based Coagulants Sorghum Bicolor and Trifolium Repens as Future Alternatives for Textile Wastewater Treatment Based on Computational Model. (2024). Journal of Global Humanities and Social Sciences, 5(3), 106-113. https://doi.org/10.61360/BoniGHSS242016120301

Similar Articles

1-10 of 67

You may also start an advanced similarity search for this article.